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In the menu bar, click Module, then Module Properties, then click on the dropdown "Expansion Chip". Konami VRC6 is my personal favourite. ;D
Also, welcome to the forums. Hope you have a nice time here!
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"im going to continue making this crazy stuff then after a while my style will be so sick that you will be like damn suuun that shit is so sick i dont even get it. i will be like bro its ok.. you dont have to." -omgdonut
Just remember that as this program is designed to allow music design for Nintendo Famicom/NES video game consoles, you can't just [i]add[/i] a second triangle channel or run six DPCM channels. You're stuck with channels that the default RP2A03 sound chip (two pulse, triangle, noise, DPCM) and whatever expansion chip you choose provide.
You can find more information about the sound chips and their capabilities (among other things) in the [url=http://famitracker.com/wiki/index.php?title=Sound_hardware]Wiki.